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Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor

Received: 29 January 2019     Accepted: 11 March 2019     Published: 25 March 2019
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Abstract

In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.

Published in International Journal of Computational and Theoretical Chemistry (Volume 7, Issue 1)
DOI 10.11648/j.ijctc.20190701.15
Page(s) 28-34
Creative Commons

This is an Open Access article, distributed under the terms of the Creative Commons Attribution 4.0 International License (http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution and reproduction in any medium or format, provided the original work is properly cited.

Copyright

Copyright © The Author(s), 2019. Published by Science Publishing Group

Keywords

Colorimetric Sensor, IR Sensing, Fluoride Anion Recognition, Hydrogen Bonding, DFT Calculations, Acoyl Hydrazones

References
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Cite This Article
  • APA Style

    Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. (2019). Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. International Journal of Computational and Theoretical Chemistry, 7(1), 28-34. https://doi.org/10.11648/j.ijctc.20190701.15

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    ACS Style

    Noorain Khalifa; Shibin Jasper Thomas; Nithin Kota Vasudeva Upadhya; Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int. J. Comput. Theor. Chem. 2019, 7(1), 28-34. doi: 10.11648/j.ijctc.20190701.15

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    AMA Style

    Noorain Khalifa, Shibin Jasper Thomas, Nithin Kota Vasudeva Upadhya, Sreeja Puthenveettil Balakrishnan. Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor. Int J Comput Theor Chem. 2019;7(1):28-34. doi: 10.11648/j.ijctc.20190701.15

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  • @article{10.11648/j.ijctc.20190701.15,
      author = {Noorain Khalifa and Shibin Jasper Thomas and Nithin Kota Vasudeva Upadhya and Sreeja Puthenveettil Balakrishnan},
      title = {Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor},
      journal = {International Journal of Computational and Theoretical Chemistry},
      volume = {7},
      number = {1},
      pages = {28-34},
      doi = {10.11648/j.ijctc.20190701.15},
      url = {https://doi.org/10.11648/j.ijctc.20190701.15},
      eprint = {https://article.sciencepublishinggroup.com/pdf/10.11648.j.ijctc.20190701.15},
      abstract = {In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.},
     year = {2019}
    }
    

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  • TY  - JOUR
    T1  - Investigation of 2-Hydroxyacetophenone Nicotinic Acid Hydrazone as a Fluoride Sensor
    AU  - Noorain Khalifa
    AU  - Shibin Jasper Thomas
    AU  - Nithin Kota Vasudeva Upadhya
    AU  - Sreeja Puthenveettil Balakrishnan
    Y1  - 2019/03/25
    PY  - 2019
    N1  - https://doi.org/10.11648/j.ijctc.20190701.15
    DO  - 10.11648/j.ijctc.20190701.15
    T2  - International Journal of Computational and Theoretical Chemistry
    JF  - International Journal of Computational and Theoretical Chemistry
    JO  - International Journal of Computational and Theoretical Chemistry
    SP  - 28
    EP  - 34
    PB  - Science Publishing Group
    SN  - 2376-7308
    UR  - https://doi.org/10.11648/j.ijctc.20190701.15
    AB  - In the present work, we studied the selective chemosensing behavior of 2- hydroxyacetophenone nicotinic acid hydrazone (H2L) with fluoride anion. Theoretical and experimental tools were deployed to understand the mechanism of sensing. Experimentally, upon the addition of fluoride to H2L, a change in colour was observed. The 1H NMR spectral studies showed a change in electronic environment around the N-H and O-H bonding sites of the receptor. UV visible spectrum confirmed the formation of a new complex and IR spectrum showed the absence of the hydrogen bond donor peaks. Density Functional Theory (DFT) calculations were carried out in ground state and they were found to be in accordance with the experimental results.
    VL  - 7
    IS  - 1
    ER  - 

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Author Information
  • Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India

  • Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India

  • Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India

  • Department of Chemistry, CHRIST (Deemed to Be University), Bengaluru, India

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